Kinetics Release of Cymbopogon Citatrus Essential Oil from Starch Beads: For Food Security in Nigeria
DOI:
https://doi.org/10.47672/ajfsn.1725Keywords:
Cymbopogon Citatrus, Kinetics, Starch Beads, OilAbstract
Purpose: The essential oil of Cymbopogon citratus was extracted using a green method (i.e. essential oil still), encapsulated into cassava starch matrix using sodium alginate as a binder.
Materials and methods: The encapsulated sodium alginate starch beads were characterized using Scanning Electron Microscope (SEM) and Fourier Transform Infrared Spectrophotometer (FTIR), the release kinetics of the oil was monitored by UV-Visible Spectrophotometry from two (2) aqueous media, buffer of pH 4 and pH 9, and analysed before exploring their potential for insecticide and repellant property and controlled release.
Findings: The result for SEM showed the sodium alginate starch beads were spherical in shape, average radius of 5 µm, modal area of 0.10 µm2 and average size of 852.28 nm and were good absorbent of essential oil in which its volatility can be entrapped. Release kinetics showed its maximum peak at 2 hours and data obtained spectrophotometrically were further fitted to the various Kinetics Models such as First Order, Pseudo Second Order, Zero Order and Higuchi Order Kinetics Model from which their equations gave (R2= 0.9991, 0.9188) (K= 0.1547, 0.0738), (R2= 0.9962, 0.9201) (K= -0.0071, -0.0038), (R2= 0.9929, 0.8059) (K= 0.0065, 0.0247) and (R2= 0.8389, 0.7216) (K= 0.033, 0.0392), respectively, from the two (2) aqueous media, buffer of pH 4 and pH 9, and it followed the First Order Kinetic Model, which indicated the absorption of the encapsulated essential oil into the porous material of the sodium alginate starch beads and its FTIR showed the functionalities such as OH, CO, CHO, C=C, =C-H and C-H present conformed to the structure of citral, starch and algin.
Implications to Theory, Practice and Policy: The green method of the extraction of essential oils as shown in Appendix viii (i.e. the locally made essential oil still) should be improved upon to ease extraction of essential oil from barks, roots, seeds and leaves of plants.
Downloads
References
Ashgari, J. Touli, C.K. and Mazaheritehrani, M. (2010) "Microwave-assisted hydrodistillation of essential oils from Echinophora platyloba DC," Journal of Medicinal Plants Research, 6(28): 4475-4480.
Carlson, L.H., Machad, C.C., Pereira, S.C. and Bolzan, A. (2001), "Extraction of Lemongrass Essential Oil with dense Carbon-dioxide," Journal of Supercritical Fluids, 21: 33-39.
Chanthal, S., Prachakoli, S. and Ruangviriyachai, C. (2012) "Influence of extraction methodologies on the analysis of five major volatile aromatic compounds of citronella grass and lemongrass grown in Thailand". Journal of AOAC International, 4: 5-7.
Food and Agriculture Organization of the United Nations (2002), International Code of Conduct on the Distribution and Use of Pesticides. National Resources Management and Environment Department, FAO, Rome, 11: 247-261
Hina, K.S., Kshirasagar R.V. and Patil S.G. (2015), "˜Mathematical Models for Drug Release Characterization'. World Jornal of Pharmacy and Pharmaceutical Sciences: School of Pharmacy Swami Ramanand Teerth Marathwada University, Nanded-431606. ISSN2278-4357, 8: 127-30.
Paviani, L., Pergher, S.L.C. and Dariva, C. (2006) "Application of molecular sieves in the fractionation of lemongrass oil from high-pressure carbon dioxide extraction," Brazilian Journal of Chemical Engineering, 23: 219-22.
Tajidin, K.C., Ahmad, S.H., Azimah, A.B. and Munirah, M. (2012), "Chemical composition and citral content in lemon grass (Cymbopogon citratus) essential oil at three maturity stages," International Journal of Biotechnology, 11(11): 2685-2693.
Tian S, Xue X, Wang X and Chen Z (2022) Preparation of starch-based functional food nano-microcapsule delivery system and its controlled release characteristics. Front. Nutr. 9:982370. doi: 10.3389/fnut.2022.982370
Vieira, M.V.; Pastrana, L.M.; Fuciños, P. (2020). Microalgae Encapsulation Systems for Food, Pharmaceutical and Cosmetics Applications. Mar. Drugs 2020, 18, 644
Wang, J., Hu, X., Chen, J., Wang, T., Huang, X., Chen, G. (2022). The Extraction of β-Carotene from Microalgae for Testing Their Health Benefits. Foods. 11, 502. https://doi.org/10.3390/foods11040502
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Itodo, I. N, Ada Gabriel, Nnamonu, L. A, Tor-Anyii, T. A.
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution (CC-BY) 4.0 License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.